Reductive arene ortho-silanolization of aromatic esters with hydridosilyl acetals.
نویسندگان
چکیده
This work describes the design and application of a single-pot, reductive arene C-H silanolization of aromatic esters for synthesis of ortho-formyl arylsilanols. This strategy involves a sequence of two transition metal (Ir and Rh)-catalyzed reactions for reductive arene ortho-silylation directed by hydridosilyl acetals and hydrolysis.
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ورودعنوان ژورنال:
- Chemical communications
دوره 51 18 شماره
صفحات -
تاریخ انتشار 2015